Dust emission calculations in open storage piles protected by means of barriers, CFD and experimental tests

The importance of open mineral storage piles in bulk solids port terminals have increased considerably in recent years in Europe and USA (in Spain, great extensions of transoceanic ports are being made) to address the increasing demand of raw material importation due to local mining operation closure. These storage piles are affected by the climatologically processes and the dust emission to the atmosphere, causing repercussions to health and environmental, which is intimately related to the air velocity, according to USEPA studies, maximum ratio of dust emission emitted from CFD and software Ansys CFX 10.0 is determined. In addition, an emission variability study based on the pile distance of different height solid barriers is developed, reducing the emission to 66%. The studies have been contrasted by published investigations and industrial measurement.     

The inflationary effects of environmental fluctuations ensure the persistence of sink metapopulations

Under current rates of environmental change many populations may be found in habitats of low quality and low conservation value, creating population sinks. We test recent theory that suggests, surprisingly, that stochastic environmental variability may enhance the long-term persistence of sink metapopulations. Using experimental populations of Paramecium aurelia we show that it is possible for a metapopulation comprised entirely of sink populations to persist for many generations in a random environment. In accordance with the theory, we show that positive temporal autocorrelation and low spatial correlation in the environment can ensure the long-term persistence and enhance the mean and maximum abundance of sink metapopulations. High levels of spatial correlation in the environment created strong population synchrony and limited the persistence time of the sink metapopulations. These results have important implications for the development of a theory underlying the synergistic effects of habitat fragmentation and environmental change on population persistence.     

Measurements of selected PCBs in open urban ambient air of Madrid (Spain)

The focus of this study was to characterize the concentration levels of selected PCBs and compare them to compiled data in order to contribute to the international database. The sampling site is located in the outskirts of Madrid and can be considered an open urban area. 32 samples of air were taken from February 1998 to June 1998 by using a high volume air sampler. Glass fiber filters and polyurethane foam (PUF) were used to collect the paniculate and gas phase material, respectively. PUF plugs were Soxhlet extracted and filters were ultrasonically extracted by using pesticide-grade hexane and dichloromethane, respectively. The cleanup procedure was carried out on a florisil column with hexane and hexane/dichloromethane as elution solvents. GC/MS in a selected ion monitoring mode was used for quantification and 29 selected PCBs congeners were analyzed.     

Pharmaceutical compound removal efficiency by a small constructed wetland located in south Brazil

Environmental Science and Pollution Research - The fate of pharmaceuticals during the treatment of effluents is of major concern since they are not completely degraded and because of their...     

Complex biological responses to the experimental acidification of Little Rock Lake, Wisconsin, USA

Acidification can affect aquatic organisms directly through hydrogen ion toxicity, and indirectly through disrupted food web dynamics and altered abiotic conditions. Field populations from selected taxa were studied during the Little Rock Lake whole-basin acidification experiment to illustrate patterns whose timing suggests direct (i.e. immediate) or indirect (i.e. delayed or non-uniform) responses to pH change. As the treatment basin was acidified to pH 5.6, 5.2 and 4.7, immediate changes consistent with a direct pH response were observed for species representing several trophic levels. For other taxa (e.g. littoral invertebrates associated with filamentous algal mats, several species of pelagic zooplankton), indirect mechanisms induced by food web changes were more likely explanations for abundance patterns. The results presented here suggest that the responses of aquatic ecosystems to acidification involve a complex interplay between direct pH effects and subsequent indirect interactions.     

Chemical compounds of the foraging recruitment pheromone in bumblebees

When the frenzied and irregular food-recruitment dances of bumblebees were first discovered, it was thought that they might represent an evolutionary prototype to the honeybee waggle dance. It later emerged that the primary function of the bumblebee dance was the distribution of an alerting pheromone. Here, we identify the chemical compounds of the bumblebee recruitment pheromone and their behaviour effects. The presence of two monoterpenes and one sesquiterpene (eucalyptol, ocimene and farnesol) in the nest airspace and in the tergal glands increases strongly during foraging. Of these, eucalyptol has the strongest recruitment effect when a bee nest is experimentally exposed to it. Since honeybees use terpenes for marking food sources rather than recruiting foragers inside the nest, this suggests independent evolutionary roots of food recruitment in these two groups of bees.     

拉普拉塔河流域以及巴塔哥尼亚地区及相关海域水生态栖息地的改变

本文描述了南美大陆南部陆地和东南沿海地区环境特性及水生栖息地和群落的现状(GIWA巴塔哥尼亚大陆架亚区),结果来自一项GIWA项目框架任务所完成的一份全面评估,绝大部分依据的是公开发表的数据.分析主要集中在跨边界水资源目前的情况和人类活动带来的影响.内陆水体的栖息地和群落变化主要是由为发电和其他用途而建的水坝和水库引起的.从活水环境到净水环境影响了生境,造成了生物群落的改变.在拉普拉塔(La Plata)河流域,外来入侵物种使本地物种消失.过度捕捞和污染影响了生物多样性,造成了海洋栖息地质量下降.本篇文章讨论了相关的原因,讨论了布宜诺斯艾利斯省和渔业资源由两国共享的阿根廷-乌拉圭公共渔业区对沿海生态环境的政策选择.     

Photocatalytic degradation of atrazine by porphyrin and phthalocyanine complexes

This study principally focused on a new kind of photochemical reaction catalyst: porphyrin and phthalocyanine complexes. In a first step, the preparation of the catalysts was optimized. A resin has been chosen to be the support of the complexes. Efficiency of catalytic activity is performed on the degradation of a pesticide: atrazine. The best atrazine degradation occurs with 4.6% of complexes versus substrate. The role of the surface has also been shown to be important. Then, their performances were demonstrated in terms of kinetics and degradation routes, compared to a classical catalyst: titanium dioxide. This study seeks to assess the efficiency of these systems both in a mercury lamp reactor and under solar irradiation which reduces energy costs. The best atrazine degradation half-life found for the complexes is about 200 min with the iron phthalocyanine. These catalysts exhibit particular oxidation activities. Indeed, the degradation routes have been found different between the semi-conductor and the metallic complexes. These complexes are able to cleave the triazinic ring more efficiently than the titanium dioxide.     

Vacuum-ultraviolet (VUV) photolysis of water: Mineralization of atrazine

The versatility and efficiency of the VUV photolysis of water as an “Advanced Oxidation Procedure” for the light-induced oxidative degradation of atrazine as a pollutant of surface and ground waters is evaluated. The oxidation of atrazine using TiO₂ as a photocatalyst has been reported to produce almost stoichiometric amounts of cyanuric acid. Mineralization to CO₂, water and inorganic nitrogen containing ions occurred to a very low extent implying that cyanuric acid is resistant to further degradation under the chosen experimental conditions. Our present results show that in oxygen saturated solutions 50% of the initial atrazine is converted to cyanuric acid, whereas only 10% of the initial atrazine is isolated as cyanuric acid in argon saturated solutions. The results indicate that mineralization is more efficient in not strictly oxidative reaction media.